Preparation of different manganese oxide structures via controlling the concentration and the type of the alkaline media

Said, Samer; Riad, Mary; Mikhail, Sara

doi:10.26655/AJNANOMAT.2019.2.3.4

Document Type : Original Article

Authors

Egyptian Petroleum Research Institute, Nasr City, Egypt

https://doi.org/10.26655/AJNANOMAT.2019.2.3.4

Abstract

Birnessite and manganite materials were prepared using a simple precipitation process in an alkaline medium. Potassium hydroxide and tetraethyl ammonium hydroxide (TEAH) used as the precipitating agents. Different techniques such as XRD, DSC, TGA, FT-IR, TEM and N₂ adsorption analyses were employed to characterize the prepared samples. The results revealed that the formed phase in the prepared sample is dependent on the concentration of the precipitating agent. In addition, the XRD results showed the formation of various phases through controlling the concentration of the precipitating agent. Pure phase of birnessite produced in the high alkaline medium, and manganite (γ-MnOOH) at relatively low alkalinity. The samples prepared by using TEAH were well crystalline compared with the analogue one prepared by KOH. The obtained results elaborated the role of TEAH in directing the order of the particles during the preparation step.

Graphical Abstract

Keywords

Main Subjects

Synthesis

References

[1]. Yu, J., Ph. Savage. Industrial Engineering Chemical Resresearch, 2000, 39:4014

[2]. Singh A., Fernando S. Chemical Engineering Technology, 2007, 30:1716

[3]. Meng Y., Song W., Huang H., Ren Z., Chen S.Y., Suib S. Journal of Amrican Chemical Society, 2014, 136:11452

[4]. Ahsanulhaq Q., Kim S.H., Hahn Y.B. Journal of Alloys and Compounds, 2009, 484:17

[5]. Manceau A., Lanson M., Takahashi Y., American Mineralogy, 2014, 99:2068

[6]. Yang D.S., Wang M.K. Clays-Clay Mineral, 2003, 51:96

[7]. Said S., Riad M., Helmy M., Mikhail S., Khali L. Journal of Nanostructure Chemistry, 2016, 6:171

[8]. Said S., Riad M., Helmy M., Mikhail S., Khali L. Chemical Material Research, 2014, 6:27

[9]. Kitchaev D., Dacek S., Sun W., Ceder G. Journal of American Chemical Society, 2017, 139:2672

[10]. Atkins A.L., Shaw S., Peacock C.L. Geochimistry Cosmochimistry Acta, 2014 144:109

[11]. Regmi R., Tackett R., Lawes G. Journal of Management Material, 2009, 321:2296

[12]. Athouel L., Arcidiacono P., Ramirez-Castro C., Crosnier O., Hamel C., Dandeville Y., Guillemet P., Scudeller Y., Guay D., Belanger D., et al. Electrochimical Acta, 2012, 86:268

[13]. Villalobos M., Escobar-Quiroz I.N., Salazar-Camacho C. Geochimstry. Cosmochimistry. Acta, 2014, 125:564

[14]. Liu G., Chen L., Yu J., Feng N. Applied Catalysis A: General, 2018, 568:157

[15]. Zhang G., Liu Y., Guo F., Hu Y., Liu X.Z., Qian Y. Solid State Communcation, 2005, 134:523

[16]. Saad L., Sobhi Z., Mikhail S. Egyptian Journal of Petroleum, 2002, 11:67

[17]. Tiana X., Yang L., Qing X., Yu K., Wang X., Sensor Actua. B., 2015, 207:34

[18]. Misnon I.I., Abd Aziz R., Zain N.K., Vidhyadharan M. B., Krishnan S.G., Jose R., Material Research Bulletin, 2014, 57:221

[19]. Huang M., Zhang Y.X., Li F., Zhang L.L., Ruoff R.S., Wen Z.Y., Liu Q. Science Rep., 2014, 4:3878

[20]. Yan D., Zhang H., Li S., Zhu G., Wang Z., Xu H., Yu A. Journal of Alloys and Compdounds, 2014, 607:245

[21]. Ghaly M., El-Dars F., Hegazy M., Abdel Rahman R. Chemical Engineering Journal, 2016, 284:1373

[22]. Nakayama M., Nishiyama M., Shamoto M., Tanimoto T., Tomono K., Inoue R. Journal Electrochemical Society, 2012, 159:1176

[23]. Dinnebier E., Billinge J. Powder Diffraction Theory and Practice The Royal Society of Chemistry, 2008; p 1-583

[24]. Lefkowitz J., Elzing E. Chemical Geology, 2017, 466:524

[25]. De Wolff P.M. Acta Crystallography, 1959, 12:341

[26]. Gai J., Liu J., Suib S. Chemical Material, 2002, 14:2071

[27]. Atique Ullah A.K.M., Fazle Kibria A.K.M., Akter M., Khan M.N.I., Maksud M.A., Jahan R.A., Firoz S.H. Journal of Saudi Chemical Society, 2017, 21:830

[28]. Vro D., Brsn L., Posr J. Amircan Mineralogy, 1989, 74:177

[29]. Zhang W., Yang Z., Liu Y., Tang S., Han X., Chen M. Journal of Crystal Growoth, 2004, 263:394

[30]. Liu G., Liao S., Zhu D., Hua Y., Zhou W. Chemical Engineering Journal, 2012, 213:286

[31]. Zhang W., Yang Z., Liu Y. Journal of Crystal Growoth, 2004, 263:394

[32]. Sharma P., Whittingham M. Material Letter, 2001, 48:319

[33]. Kang L., Zhang M., Liu Z.H., Ooi K. Spectrochimica Acta. A., 2007, 67:864

[34]. Potter R., Rossman G. Amrican Minerology, 1979, 64:1199

[35]. Kohler T., Armbrustor T., Libowitzky E. Journal of Solid State Chemistry, 1997, 133:486

[36]. Rives V., Prieto O., Del Arco M. Thermochima Acta., 2003, 401:95

[37]. Zhang Y., Qin Z., Wang G., Zhu H. Dong M., Li S., Wu Z., Li Z., Wu Z., Zhang J. Applied Catalysis Environmental B., 2013, 129:172

[38]. Xi G., Peng Y., Zhu Y., Xu L., Zhang W., Yu W., Qian Y. Material Research Bulletin, 2004, 39:1641

[39]. Li Y., Wei D., Du Y. Chemosphere, 2015, 119:282

Asian Journal of Nanoscience and Materials

Preparation of different manganese oxide structures via controlling the concentration and the type of the alkaline media

References

References

Volume 2, Issue 3
July 2019
Pages 286-300

Preparation of different manganese oxide structures via controlling the concentration and the type of the alkaline media

References

References

Volume 2, Issue 3July 2019Pages 286-300

Volume 2, Issue 3
July 2019
Pages 286-300