Synthesis of γ-Fe2O3 Nanoparticles and Catalytic activity of Azide-Alkyne Cycloaddition Reactions

Sudhakara, K; Praveen Kumar, Avvaru; Kumar, Begari Prem; Raghavender, A; Ravi, S; Keniec, Dunkana Negussa; Lee, Yong-Ill

doi:10.26655/AJNANOMAT.2022.4.1

Document Type : Original Article

Authors

¹ Rural Development Society, R&D centre, Punjagutta, Hyderabad, India, 500082

² Department of Chemistry, College of Natural and Computational Science, Wollega University, Nekemte-P.O. Box: 395, Ethiopia

³ Department of Chemistry, Changwon National University, Changwon 641-773, Republic of Korea

https://doi.org/10.26655/AJNANOMAT.2022.4.1

Abstract

Iron nanoparticles (NPs), due to their interesting properties, low cost preparation and many potential applications in ferrofluids, magneto-optical, catalysis, drug delivery systems, magnetic resonance imaging, and biology, have attracted a lot of interest during recent years. In this research, γFe2O3NPs were synthesized through simple co-precipitation method followed by thermal treatment at 300 °C for 2 hours. In our synthesis route, FeCl3 and FeCl2 were employed as precursors to synthesize γ-Fe2O3NPs. This approach is very effective and economical. The γ-Fe2O3NPs were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM),and vibrating sample magnetometer (VSM). The XRD and FT-IR results indicated the formation of γ-Fe2O3NPs. The SEM and TEM images contributed to the analysis of particle size and revealed that the γ-Fe2O3 particle size of the nanopowders ranged from 11 and 13 nm. Magnetic property was measured by VSM at room temperature and hysteresis loops exhibited that the γ-Fe2O3 NPs were super-paramagnetic. The synthesized γ-Fe2O3NPs were applied in order to synthesize mono-triazoles within one molecule using azide-alkyne cycloaddition reactions. KEYWORDS: γ-Fe2O3 Nanoparticles,

Graphical Abstract

Keywords

Main Subjects

Nanocatalyst

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Asian Journal of Nanoscience and Materials

Synthesis of γ-Fe2O3 Nanoparticles and Catalytic activity of Azide-Alkyne Cycloaddition Reactions

References

References

Volume 5, Issue 4
December 2022
Pages 243-251

Synthesis of γ-Fe2O3 Nanoparticles and Catalytic activity of Azide-Alkyne Cycloaddition Reactions

References

References

Volume 5, Issue 4December 2022Pages 243-251

Volume 5, Issue 4
December 2022
Pages 243-251