Document Type: Original Article

Authors

1 Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran.

2 Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

3 Institute of Physic of the Czech Academy of Sciences, Na Slovance 2, 182 21 Prague, Czech Republic

Abstract

Nano-sized powder of a new 1D copper(I) coordination polymer, [Cu(nba2en)(NCS)]n (1), (nba2en = N,Nʹ-bis(4-ntrobenzylidene)ethane-1,2-diamine, was synthesized using ultrasonic bath assisted and characterized by scanning electron microscopy (SEM), IR and 1H-NMR spectroscopy, and elemental analyses. Thermal stability of 1 was studied using thermogravimetric (TG) and differential thermal analyses (DTA). The crystal structure was investigated by single-crystal X-ray diffraction. The structure of 1 consists of a 1D polymeric chain in which copper(I) ions are bridged by two thiocyanate group bonding in an end-to-end fashion, with CuCu separation 5.556(4) Å.

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[1] Zhang D, Wang P (2012) Inorg Chem Commun 26:77-81.

[2] Mondal S, Mandal S, Jana A, Mohanta S (2014) Inorg Chim Acta 415:138-145.

[3] Li Y, Zhang ZX, Li T, Li KC (2010) Russ J Coord Chem 36:48-52.

[4] Kim TH, Shin YW, Kim JS, Lee SS, Kim J (2007) Inorg Chem Commun 10:717-719.

[5] Bigdeli F, Ghasempour H, Azhdari Tehrani A, Morsali A, Hosseini-Monfared H (2017) Ultrasonic Sonochem 37:29-36.

[6] Masoomi MY, Morsali A, Junk PC, Wang J (2017) Ultrasonic Sonochem 34:984-992.

[7] Khalaji AD, Rohlicek J, Machek P, Das D (2014) J Clust Sci 25:1425-1434.

[8] Khalaji AD, Jafari K, Bahramian B, Fejfarova K, Dusek M (2013) Monatsh Chem 144:1621-1626.

[9] Khalaji AD, Triki S, Das D (2011) J Therm Anal Calorim 103:779-783.

[10] Amirnasr M, Rasouli M, Mereiter K (2013) Inorg Chim Acta 404:230-235.

[11] Morshedi M, Amirnasr M, Triki S, Khalaji AD (2009) Inorg Chim Acta 362:1637-1640.

[12] Beheshti A, Clegg W, Nobakht V, Harrington RW (2014) Polyhedron 81:256-260.

[13] Khalaji AD, Weil M, Hadadzadeh H, Daryanavard M (2009) Inorg Chim Acta 362:4837-4842.

[14] Khalaji AD, Stoeckli-Evans H, Das D (2012) Monatsh Chem 143:595-600.

[15] Palatinus L, Chapuis G (2007) J Appl Crystallogr 40:786-791.

[16] Petricek V, Dusek M, Palatinus L (2014) Z Kristallogr 229:345-350.

[17] Diamond-Crystal and Molecular Structure Visualization. Crystal Impact - K.