The study of range-scaling transformation of nanoparticle compounds on thin films of gold-centered monolayer protected nanoparticles by molecular modeling

Shahpar, Mehrdad; Esmaeilpoor, Sharmin

doi:10.26655/ajnanomat.2018.1.1

Document Type : Original Article

Authors

¹ Director of Ilam Petrochemical Company

² Department of Chemistry, Payame Noor University, P.O. BOX 19395-4697, Tehran, Iran

https://doi.org/10.26655/ajnanomat.2018.1.1

Abstract

A quantitative structure–retention relation (QSRR) study was conducted on the range-scaling transformation (Xa) of the nanoparticle compounds which obtained by comprehensive two-dimensional gas chromatography (GC×GC) stationary phases consisting of thin films of the gold-centered monolayer protected nanoparticles (MPNs) system. The genetic algorithm was used as descriptor selection and model development method. Modeling of the relationship between the selected molecular descriptors and the retention time was achieved by linear (partial least square; PLS) and nonlinear (Levenberg-Marquardt artificial neural network; L-M ANN) methods. Linear and nonlinear methods resulted in an accurate prediction whereas more accurate results were obtained by L-M ANN model.

Graphical Abstract

Keywords

Main Subjects

Analytical chemistry

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Asian Journal of Nanoscience and Materials

The study of range-scaling transformation of nanoparticle compounds on thin films of gold-centered monolayer protected nanoparticles by molecular modeling

References

References

Volume 1, Issue 1 - Serial Number 1
March 2018
Pages 1-10

The study of range-scaling transformation of nanoparticle compounds on thin films of gold-centered monolayer protected nanoparticles by molecular modeling

References

References

Volume 1, Issue 1 - Serial Number 1March 2018Pages 1-10

Volume 1, Issue 1 - Serial Number 1
March 2018
Pages 1-10