Document Type: Original Article

Authors

1 Department of Food Hygiene, Ayatollah Amoli Branch, Islamic Azad University, Amol 46311-39631, Mazandaran, Iran

2 Department of Food Science and Technology, Ayatollah Amoli Branch, Islamic Azad University, Amol 46311-39631, Mazandaran, Iran

Abstract

In this study, MgO/CNTs nanocomposite was synthesized using a simple approach according to the hydrogen bonding between the oxygen atom in MgO and hydrogen atom in SWCNTs-COOH. The nanocomposite was characterized using the FESEM and EDS methods. The MgO/CNTs nanocomposite was used for amplification of the paste electrode (PE) at the presence of 1-methyl-3-buthyl imizazolonium tetrafluoroborate (MBITF) as the binder. The MgO/CNTs/MBITF/PE was used as an electroanalytical tool for electro-oxidation determination of vitamin B6 in food samples. In comparison to PE, the oxidation signal of vitamin B6 was improved up to 3.2 times at the surface of MgO/CNTs/MBITF/PE. At pH=6 as optimum condition, the MgO/CNTs/MBITF/PE revealed linear dynamic range of 0.1-400 µM for determination of vitamin B6 with the detection limit of 30.0 nM. In the final step, the MgO/CNTs/MBITF/PE showed acceptable recovery data for the determination of vitamin B6 in fruit juices samples, confirming the ability of the sensors in real sample analysis.

Graphical Abstract

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Main Subjects

[1]. Metzler D.E., Ikawa M., Snell E.E. Am. Chem. Soc., 1954, 76: 648

[2]. Heaney R.P. Am J Clin Nutr., 2003, 78:350

[3]. O'neil CE., Nicklas TA., Keast DR., Fulgoni VL. Food Nutr. Res., 2014, 58:15784

[4]. Johansson S., Lindstedt S., Tiselius H.G. J. Biol. Chem., 1974, 249:6040

[5]. Hunt J.R. Nutr. Rev., 2002, 60:127

[6]. Drewnowski A. Front Nutr., 2019, 6:37

[7]. Kuchinskas E.J., Horvath A., Vigneaud V. Arch Biochem Biophys., 1957, 68:69

[8]. Ebbing M., Bønaa K.H., Nygård O., Arnesen E., Ueland P.M., Nordrehaug J.E. JAMA., 2009, 302:2119

[9]. Riggs K.M. Am J Clin Nutr., 1996, 6:3306

[10]. Wyatt K.M., Dimmock P.W., Jones P.W., O'Brien P.S. BMJ Clin. Res., 1999, 318:1375

[11]. Kashanian M., Mazinani R., Jalalmanesh S. Int. J. Gynaecol. Obstet., 2007, 96:43

[12]. Niebyl J.R. N. Engl. J. Med., 2010, 363:1544

[13]. Matthews A., Haas D.M., O'Mathúna DP., Dowswell T. Sao Paulo Med J., 2011, 129:55

[14]. Jacobsen D.W., Gatautis V.J., Green R., Robinson K., Savon S.R., Secic M. Clin. Chem., 1994, 40:873

[15]. Yagi T., Iwamoto S., Mizuseki R., Furuya M., Nakayama K. J. Nutr. Sci. Vitaminol., 2013, 59:9

[16]. Sampson D., Eoff L., Yan X., Lorenz K. Cereal Chem., 1995, 72:217

[17]. Kall M.A. Food Chem., 2003, 82:315

[18]. Atkin L., Schultz A., Williams W., Frey C. Ind. Eng. Chem., Anal. Ed., 1943, 15:141

[19]. Scudi J.V. J. Biol. Chem., 1941, 139:707

[20]. Nepote A.J., Damiani P.C., Olivieri A.C. J. Pharm. Biomed. Anal., 2003, 31:621

[21]. Teixeira M.F.S., Marino G., Dockal E.R., Cavalheiro ÉTG. Anal. Chim. Acta., 2004, 508:79

[22]. Baghayeri M., Mahdavi B., Hosseinpor‐Mohsen Abadi Z., Farhadi S., Appl. Organomet. Chem., 2018, 32:e4057               

[23]. Baghayeri M., Rouhi M., Lakouraj M.M., Amiri-Aref M. J. Electroanal. Chem., 2017, 784:69             

[24]. Baghayeri M., Alinezhad H., Fayazi M., Tarahomi M., Ghanei-Motlagh R., Maleki B., Electrochim. Acta., 2019, 312:80

[25]. Maleki B., Baghayeri M., Abadi S.A.J., Tayebee R., Khojastehnezhad A. RSC Adv., 2016, 6:96644   

[26]. Golikand A.N., Raoof J., Baghayeri M., Asgari M., Irannejad L. Russ. J. Electrochem., 2009, 45:192

[27]. Baghayeri M., Ansari R., Nodehi M., Razavipanah I., Veisi H. Microchim. Acta, 2018, 185:320       

[28]. Anbarsooz M., Amiri M., Rashidi I., Javadi M. Curr. Biochem. Eng., 2020, 6:72

[29]. Alizadeh M., Azar P.A., Mozaffari S.A., Karimi-maleh H., Tamaddon A.M. Front. Chem., 2020, 8:677

[30]. Arabali V., Malekmohammadi S., Karimi F. Microchem. J., 2020, 158:105179        

[31]. Hojjati-Najafabad A., Rahmanpour M.S., Karimi F., Zabihi-Feyzaba H., Malekmohammadi S., Agarwal S., Gupta V.K., Int. J. Electrochem. Sci., 2020, 15:6969      

[32]. Zabihpour T., Shahidi S.A., Karimi Maleh H., Ghorbani-HasanSaraei A. Eurasian Chem. Commun., 2020, 2:362

[33]. Golikand A.N., Raoof J., Baghayeri M., Asgari M., Irannejad L. Russ. J. Electrochem., 2009, 45:192

[34]. Davarnia B., Shahidi S.A., Karimi-Maleh H., Ghorbani-Hasan Saraei A., Karimi F. Int. J. Electrochem. Sci., 2020,15:2549

[35]. Beitollahi H., Mohadesi A., Ghorbani F., Karimi-Maleh H., Baghayeri M., Hosseinzadeh R. Chin. J. Catal., 2013, 34:1333

[36]. Targhoo A., Amiri A., Baghayeri M., Microchim Acta., 2018, 185:15

[37]. Brunetti B., Desimoni E. J. Food Compost. Anal., 2014, 33:155